Radiation-grafted membrane/electrode assemblies with improved interface

被引：55

作者：

Huslage, J ^{[1
]}

Rager, T ^{[1
]}

Schnyder, B ^{[1
]}

Tsukada, A ^{[1
]}

机构：

[1] Paul Scherrer Inst, Lab Elektrochem, CH-5232 Villigen, Switzerland

来源：

ELECTROCHIMICA ACTA | 2002年 / 48卷 / 03期

关键词：

polymer electrolyte fuel cell; membrane/electrode interface; Nafion (R)-coating; hot-pressing; X-ray photoelectron spectroscopy;

D O I：

10.1016/S0013-4686(02)00621-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Recent progress is reported in preparing membrane/electrode assemblies for polymer electrolyte fuel cells based on radiation-grafted FEP-g-poly(styrenesulfonic acid) membranes. MEAs with an improved interface between the membrane and commercially available gas diffusion electrodes were obtained by Nafion((R))-coating of the membrane and hot-pressing. These improved MEAs showed both, performance data comparable to those of MEAs based on Nafion((R)) 112 and an operation lifetime in H-2/O-2 fuel cells of more than 2000 h at 60 degreesC and 500 mA cm(-2) current density. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：247 / 254

页数：8

共 58 条

[1]

AGOSTINO VFD, 1977, Patent No. 4012303

[2]

Beamson G., 1992, ADV MATER, DOI DOI 10.1002/ADMA.19930051035

[3]

Becker W, 2000, CHEM-ING-TECH, V72, P1541, DOI 10.1002/1522-2640(200012)72:12<1541::AID-CITE1541>3.0.CO

[4]

2-Y

[5]

Becker W, 1999, ANGEW MAKROMOL CHEM, V273, P57

[6]

Brack H. P., 1997, POLYM MAT SCI ENG, V77, P368

[7]

Brack HP, 2000, MATER RES SOC SYMP P, V575, P259

[8]

Brack HP, 2000, ACS SYM SER, V744, P174

[9]

BRACK HP, 1999, 2 S POLYM EL FUEL CE

[10]

BRUNEA JA, 1998, Patent No. 1011218

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