A new family of homoleptic Ir(III) complexes: Tris-pyridyl azolate derivatives with dual phosphorescence

被引：113

作者：

Yeh, Yu-Shan

Cheng, Yi-Ming

Chou, Pi-Tai ^{[1
]}

Lee, Gene-Hsiang

Yang, Cheng-Han

Chi, Yun

Shu, Ching-Fong

Wang, Chih-Hsiang

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[2] Natl Taiwan Univ, Instrumentat Ctr, Taipei 106, Taiwan

[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

[4] Natl Tsing Hua Univ, Dept Appl Chem, Hsinchu 300, Taiwan

来源：

CHEMPHYSCHEM | 2006年 / 7卷 / 11期

关键词：

charge transfer; density functional calculations; iridium; osmium; UV/Vis spectroscopy;

D O I：

10.1002/cphc.200600461

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Figure Presented) Blue-emitting complexes: Iridium complexes (see figure) exhibit dual phosphorescence. The blue phosphorescence at room temperature, attributed to TILCT→TLLCT conversion, occurs via a high energy barrier (∼6.9 kcal mol-1) resuiting from large-amplitude motions, such as partial twisting of the chelate groups which flip the orbital configuration and consequently results in dual phosphorescence. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：2294 / 2297

页数：4

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