Novel structural determination of a bilayer network formed by a tripodal lipophilic amide in the presence of anions

被引:32
作者
Danby, A
Seib, L
Alcock, NW
Bowman-James, K [1 ]
机构
[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
关键词
D O I
10.1039/a909341i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of a protonated tripodal lipophilic amide, N-{2-[bis(2-octanoylaminoethyl)amino]ethyl}octanamide, identified an elegantly architected bilayer hydrogen bonded structure consisting of ladder-like cascades of the amide, with the rungs comprised of the lipophilic tails pointing inward and the poles made up of polar quaternary ammonium heads lining channels filled with nitrate ions.
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页码:973 / 974
页数:2
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