Enantioselective Diels-Alder reactions between cyclopentadiene and alpha,beta-acetylenic aldehydes catalyzed by a chiral super Lewis acid

被引:44
作者
Corey, EJ
Lee, TW
机构
[1] Dept. of Chem. and Chemical Biology, Harvard University, Cambridge
关键词
D O I
10.1016/S0040-4039(97)01287-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first examples of catalytic enantioselective Diels-Alder reactions of cyclopentadiene and alpha,beta-acetyleptic aldehydes such as Bu3SnC=CCHO are described. (C) 1997 Elsevier Science Ltd.
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页码:5755 / 5758
页数:4
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