Effect of electrolytes on the physicochemical behaviour of sodium dodecyl sulphate micelles

被引:167
作者
Dutkiewicz, E [1 ]
Jakubowska, A [1 ]
机构
[1] Adam Mickiewicz Univ Poznan, Dept Phys Chem, PL-60780 Poznan, Poland
关键词
sodium dodecyl sulphate; micellization parameters; ion effect; conductivity;
D O I
10.1007/s00396-002-0723-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The values of the critical micelle concentration (cmc) and the degree of electrolytic micelle dissociation, a, for sodium dodecyl sulphate (SDS) as a function of the concentrations of the electrolytes added, NaCl, KCl, NaF, NaClO4, NH4ClO4, and Mg(ClO4)(2), have been determined. The values of the SDS cmc have been shown to depend on the kind and concentration of the electrolyte cations. The electrolyte cations cause a decrease of the cmc in the following order: Na+<NH4+<K+<Mg2+. Moreover, a depends on the kind and concentration of the electrolyte added. The electrolyte anions have a much smaller effect on the values of a than the cations. The anions enhance a in the following order: F- > ClO4- > Cl-. The effect of different electrolyte cations on a is observed; moreover the values of a either increase or decrease with the electrolyte concentration. Other micellization parameters of SDS versus the concentration of the electrolytes added have been calculated.
引用
收藏
页码:1009 / 1014
页数:6
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