Selective carbonylation routes to thiocarbamates. An alternative to phosgene

被引：43

作者：

Jones, WD ^{[1
]}

Reynolds, KA

Sperry, CK

Lachicotte, RJ

Godleski, SA

Valente, RR

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[2] Eastman Kodak Co, Rochester, NY 14650 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 09期

关键词：

D O I：

10.1021/om990931n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route for the synthesis of thiocarbamates using a transition metal complex and CO as a replacement for phosgene has been discovered. The complex (PPh3)(2)PdCl2 reacts with N-benzylmethylamine, 4-chlorobenzenethiol, and CO to selectively generate a thiocarbamate. Kinetic studies and the isolation of several intermediates in this reaction allow for the proposal of a mechanistic scheme.

引用

页码：1661 / 1669

页数：9

共 33 条

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