Cu2O Nanocube-Catalyzed Cross-Coupling of Aryl Halides with Phenols via Ullmann Coupling

被引：69

作者：

Kim, Jee Young ^{[2
]}

Park, Ji Chan ^{[1
]}

Kim, Aram ^{[2
]}

Kim, A. Young ^{[2
]}

Lee, Hyun Ju ^{[2
]}

Song, Hyunjoon ^{[1
]}

Park, Kang Hyun ^{[2
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 28期

基金：

新加坡国家研究基金会;

关键词：

Copper; Nanoparticles; Homogeneous catalysis; Cross-coupling; Diaryl ethers; O BOND FORMATION; C-O; N-ARYLATION; ARYLBORONIC ACIDS; SYNTHETIC METHODS; ROOM-TEMPERATURE; VINYL BROMIDES; DIARYL ETHERS; EFFICIENT; AMINES;

D O I：

10.1002/ejic.200900730

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal and air-stable uniform Cu2O nanocubes were employed in the development of a gram-scale, one-pot polyol synthesis. Herein is reported an efficient cross-coupling reaction of aryl halides and phenols with a catalytic amount (0.1 mol-%) of Cu2O nanocubes as recyclable catalyst and Cs2CO3 as the base in THF at 150 degrees C. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：4219 / 4223

页数：5

共 49 条

[1]

AALTEN HL, 1989, TETRAHEDRON, V45, P5556

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