Novel N,S- and N,Se-planar chiral [2,2]paracyclophane ligands:: synthesis and application in Pd-catalyzed allylic alkylation

被引：115

作者：

Hou, XL

Wu, XW

Dai, LX

Cao, BX

Sun, J

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kog Joint Lab Chem Synth, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 13期

关键词：

D O I：

10.1039/b002679o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel N,S- and N,Se-ligands with planar chirality derived from [2.2]paracyclophane have been synthesized and applied in palladium-catalyzed allylic alkylation reaction, in which ligands 5 and 9 with the two substituents at benzylic and benzene ring positions give the highest ee values.

引用

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页码：1195 / 1196

页数：2

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