Preparation of Highly Conductive Polypyrrole/Graphite Oxide Composites via in situ Polymerization

被引:30
作者
Gu, Z. [1 ]
Zhang, L. [1 ]
Li, C. [1 ]
机构
[1] E China Univ Sci & Technol, Key Lab Ultrafine Mat, Minist Educ, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China
来源
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS | 2009年 / 48卷 / 06期
基金
中国国家自然科学基金;
关键词
conductivity; graphite oxide; in situ polymerization; polypyrrole; ANODE MATERIAL; GRAPHITE; NANOPARTICLES;
D O I
10.1080/00222340903035576
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Graphite oxide (GO)/polypyrrole (PPy) composites with high electrical conductivity have been prepared via in situ polymerization. The bonding structures of the resulting composites were characterized by ultraviolet (UV)-visible spectra and X-ray photoelectron spectroscopy (XPS), which indicate no significant chemical interaction between PPy and GO. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) show that the GO surface is coated with a uniform PPy layer. In comparison with GO, the electrical conductivity of the composite increases by four orders of magnitude higher than that of pristine GO. The thermal stability of PPy/GO composite, characterized by thermogravimetry (TG), is higher than that of the pure GO.
引用
收藏
页码:1093 / 1102
页数:10
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