A new type of alumoxane obtained by controlled hydrolysis of N,N-dialkylcarbamato complexes of aluminium; crystal and molecular structure of [Al-4(mu(3)-O)(2)(O2CNPr2i)(8)]

被引：24

作者：

Abram, U

DellAmico, DB

Calderazzo, F

Kaskel, S

Labella, L

Marchetti, F

Rovai, R

Strahle, J

机构：

[1] UNIV TUBINGEN,INST ANORGAN CHEM,D-72076 TUBINGEN,GERMANY

[2] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 20期

关键词：

D O I：

10.1039/a703278a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aluminium(nr) N,N-diisopropylcarbamato derivative [Al-2(O2CNPr2i)(6)] undergoes hydrolysis with a stoichiometric amount of water giving the mu(3)-oxo derivative [Al-4(mu(3)-O)(2)(O(2)CNPr(i)2)(8)], which is analytically, spectroscopically and structurally characterized.

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页码：1941 / 1942

页数：2

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