Structural determination of saponins from Hedysarum polybotrys

被引:10
作者
Liu, Yi
Zhang, Qingying
Chen, Hubiao
Wang, Bin
An, Dongge
Zhao, Yuying [1 ]
机构
[1] Peking Univ, Hlth Sci Ctr, Sch Pharmaceut Sci, Dept Nat Med, Beijing 100083, Peoples R China
[2] Peking Univ, Hlth Sci Ctr, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
[3] Beijing Inst Microchem, Beijing 100091, Peoples R China
关键词
NMR; H-1; C-13; 2D NMR; Hedysarum polybotrys; saponin; soyasaponin II; soyasaponin II methyl ester;
D O I
10.1002/mrc.1903
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Four saponins (1-4) were isolated from the roots of Hedysarum polybotrys Hand.-Mazz. and obtained from Hedysarum (Tourn.) L for the first time. Their structures were identified on the basis of spectroscopic data. MS, 1D and 2D NMR including HMQC, HMBC,H-1-H-1 COSY and NOESY permitted correct assignments of all H-1 and C-13 signals of 1 and 2, and the C-13 NMR data of 2 were reported for the first time. Copyright (C) 2006 John Wiley & Sons, Ltd.
引用
收藏
页码:1128 / 1130
页数:3
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