Efficient method for ring opening of epoxides with amines by NaY zeolite under solvent-free conditions

被引：72

作者：

Kureshy, Rukhsana Ilyas ^{[1
]}

Singh, Surendra

Khan, Noor-ul Hasan

Abdi, Sayed Hasan Razi

Suresh, Eringathodi

Jasra, Raksh Vir

机构：

[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India

[2] Cent Salt & Marine Chem Res Inst, Analyt Sci Discipline, Bhavnagar 364002, Gujarat, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 264卷 / 1-2期

关键词：

epoxides; ring opening; amines; solvent-free; zeolites;

D O I：

10.1016/j.molcata.2006.09.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NaY zeolite was used as a recyclable catalyst for the ring opening of epoxides, using aliphatic and aromatic amines as nucleophile under solvent-free conditions to give the corresponding P-amino alcohols in high yields (up to 92%) with regioselectivity (100%). (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：162 / 169

页数：8

共 65 条

[1] 1,2-amino alcohols and their heterocyclic derivatives as chiral auxiliaries in asymmetric synthesis [J].