Thermogravimetric analysis of cotton fibers: Relationships with maturity and fineness

被引:51
作者
Abidi, Noureddine [1 ]
Hequet, Eric [1 ]
Ethridge, Dean [1 ]
机构
[1] Texas Tech Univ, Int Text Ctr, Lubbock, TX 79409 USA
关键词
fibers; pyrolysis; thermal properties; thermogravimetric analysis (TGA);
D O I
10.1002/app.24465
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];
摘要
In this study we investigated the relationships between the thermal properties versus maturity and fineness (H) of 80 selected cotton fiber samples. The instrument measurements for maturity and H were (1) micronaire as determined with a high-volume instrument, (2) maturity ratio and H as determined with an advanced fiber information system, and (3) gravimetric H as determined by the cut-and-weigh method. Three regions of thermal decomposition were observed between 37 and 150 degrees C for region 1, between 225 and 425 degrees C for region 11, and between 425 and 600 degrees C for region III. Complete decomposition of the fiber occurred at 600 degrees C. The results showed significant effects of the H/maturity indicators on the weight loss and the peak temperatures in regions II and III. High micronaires (coarse or very mature fibers), high maturity ratios, and low standard H values were associated with low weight losses. However, high weight losses were associated with high primary cell wall areas per unit mass. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码:3476 / 3482
页数:7
相关论文
共 16 条
[1]
*ASTM, 2001, 1445 ASTM D
[2]
Batra SK., 1998, Handbook of Fiber Chemistry
[3]
Faughey GJ, 2000, J APPL POLYM SCI, V75, P508, DOI 10.1002/(SICI)1097-4628(20000124)75:4<508::AID-APP5>3.0.CO
[4]
2-L
[5]
GOLDTHWAIT CF, 1947, TEXTILE WORLD JUL, P105
[6]
Characterizing the noncellulosics in developing cotton fibers [J].
Hartzell-Lawson, MM ;
Hsieh, YL .
TEXTILE RESEARCH JOURNAL, 2000, 70 (09) :810-819
[7]
Creation of a set of reference material for cotton fiber maturity measurements [J].
Hequet, Eric F. ;
Wyatt, Bobby ;
Abidi, Noureddine ;
Thibodeaux, Devron P. .
TEXTILE RESEARCH JOURNAL, 2006, 76 (07) :576-586
[8]
KLEMN D, 1998, COMPREHENSIVE CELLUL, V1
[9]
MADORSKY SL, 1958, J RES NBS RES PAP, V60, P2853
[10]
MADORSKY SL, 1956, J RES NAT STAND, V56, P2685