AFM morphological study of electropolymerised polyaniline films modified by surfactant and large anions

被引：36

作者：

Giz, MJ ^{[1
]}

Maranhao, SLD ^{[1
]}

Torresi, RM ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2000年 / 2卷 / 06期

基金：

巴西圣保罗研究基金会;

关键词：

atomic force microscopy; microscopy; polyaniline; morphology;

D O I：

10.1016/S1388-2481(00)00041-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Atomic force microscopy (AFM) ex situ experiments were carried out in order to study morphologies of polyaniline films grown in the presence of an anionic surfactant, sodium dodecylsulphate (SDS), and also using different functionalised organic acids. Polyaniline film morphologies obtained in the presence of SDS were analysed in terms of the formation of a complex between the rodlike micelles and the anilinium cation in solution. For the different acids, the influence of anion size and the solubility of the oligomeric salt were considered to explain the different sizes of globular morphologies. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：377 / 381

页数：5

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