First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF:: Co2M(PhCOO)6(TTF-CH=CHpy)2•2CH3CN, M = CoII, MnII

被引:65
作者
Gavrilenko, Konstantin S. [1 ]
Le Gal, Yann [1 ]
Cador, Olivier [1 ]
Golhen, Stephane [1 ]
Ouahab, Lahcene [1 ]
机构
[1] Univ Rennes 1, UMR 6226, CNRS, F-35042 Rennes, France
关键词
D O I
10.1039/b613191c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first paramagnetic homo- and hetero-metallic trinuclear complexes with redox active ligands derived from TTF are synthesized, the central metal ion has an octahedral coordination sphere while the outer Co-II ions are in a distorted bipyramidal surrounding, bearing TTF-ligands, the magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.
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收藏
页码:280 / 282
页数:3
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