A Soluble and Highly Conductive Ionomer for High-Performance Hydroxide Exchange Membrane Fuel Cells

被引：575

作者：

Gu, Shuang ^{[1
]}

Cai, Rui ^{[1
]}

Luo, Ting ^{[1
]}

Chen, Zhongwei ^{[1
]}

Sun, Minwei ^{[1
]}

Liu, Yan ^{[1
]}

He, Gaohong ^{[2
]}

Yan, Yushan ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Environm Chem & Engn, Riverside, CA 92521 USA

[2] Dalian Univ Technol, R&D Ctr Membrane Sci & Technol, Dalian 116012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 35期

关键词：

fuel cells; ionomers; membranes; QUATERNARY PHOSPHONIUM HYDROXIDES; DECOMPOSITION; ELECTRODE;

D O I：

10.1002/anie.200806299

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Easy cell: The new polymeric ionomer TPQPOH with a tris(2,4,6- trimethoxyphenyl)phosphonium unit has excellent solubility in some low-boiling-point water-soluble solvents, high ionic conductivity, and outstanding alkaline stability. A hydroxide exchange membrane fuel cell containing this ionomer exhibits increased peak power density and reduced internal resistance. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：6499 / 6502

页数：4

共 20 条

[1] Characterization and use of anionic membranes for alkaline fuel cells [J].

Agel, E ;

Bouet, J ;

Fauvarque, JF .

JOURNAL OF POWER SOURCES, 2001, 101 (02) :267-274

[2]

AVRAM E, 1997, PURE APPL CHEM, V34, P1701

[3] Scientific aspects of polymer electrolyte fuel cell durability and degradation [J].

Borup, Rod ;

Meyers, Jeremy ;

Pivovar, Bryan ;

Kim, Yu Seung ;

Mukundan, Rangachary ;

Garland, Nancy ;

Myers, Deborah ;

Wilson, Mahlon ;

Garzon, Fernando ;

Wood, David ;

Zelenay, Piotr ;

More, Karren ;

Stroh, Ken ;

Zawodzinski, Tom ;

Boncella, James ;

McGrath, James E. ;

Inaba, Minoru ;

Miyatake, Kenji ;

Hori, Michio ;

Ota, Kenichiro ;

Ogumi, Zempachi ;

Miyata, Seizo ;

Nishikata, Atsushi ;

Siroma, Zyun ;

Uchimoto, Yoshiharu ;

Yasuda, Kazuaki ;

Kimijima, Ken-ichi ;

Iwashita, Norio .

CHEMICAL REVIEWS, 2007, 107 (10) :3904-3951

[4] Alkaline anion-exchange radiation-grafted membranes for possible electrochemical application in fuel cells [J].

Danks, TN ;

Slade, RCT ;

Varcoe, JR .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (04) :712-721

[5] Influence of poles and polar linkings on the course pursued by elimination reactions Part V The mechanism of thermal decomposition of quaternary phosphonium hydroxides [J].

Fenton, GW ;

Ingold, CK .

JOURNAL OF THE CHEMICAL SOCIETY, 1929, :2342-2357

[6] THE BASICITY OF PHOSPHINES [J].

HENDERSON, WA ;

STREULI, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (22) :5791-5794

[7] An assessment of alkaline fuel cell technology [J].

McLean, GF ;

Niet, T ;

Prince-Richard, S ;

Djilali, N .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (05) :507-526

[8] STUDY OF POLYMERIC PHOTOSENSITIZER .2. SYNTHESES OF MULTIFUNCTIONAL POLYMERIC PHOTOSENSITIZERS CONTAINING A PENDANT NITROARYL GROUP AND A QUATERNARY PHOSPHONIUM SALT AND THEIR APPLICATION TO THE PHOTOCHEMICAL-REACTION OF POTASSIUM CINNAMATE [J].

NISHIKUBO, T ;

UCHIDA, J ;

MATSUI, K ;

IIZAWA, T .

MACROMOLECULES, 1988, 21 (06) :1583-1589

[9] Performance of solid alkaline fuel cells employing anion-exchange membranes [J].

Park, Jin-Soo ;

Park, Seok-Hee ;

Yim, Sung-Dae ;

Yoon, Young-Gi ;

Lee, Won-Yong ;

Kim, Chang-Soo .

JOURNAL OF POWER SOURCES, 2008, 178 (02) :620-626

[10] ION-SELECTIVE ELECTRODE WITH FIXED QUATERNARY PHOSPHONIUM ION-SENSING SPECIES [J].

ROCHELEAU, MJ ;

PURDY, WC .

ANALYST, 1992, 117 (02) :177-179

← 1 2 →