Anodic oxidation of hydrazine at carbon nanotube powder microelectrode and its detection

被引：156

作者：

Zhao, YD ^{[1
]}

Zhang, WD

Chen, H

Luo, QM

机构：

[1] Huazhong Univ Sci & Technol, Key Lab Biomed Photonics Minstry Educ, Wuhan 430074, Hubei, Peoples R China

[2] Inst Mat Res & Engn, 3 Res Link, Singapore 117602, Singapore

来源：

TALANTA | 2002年 / 58卷 / 03期

关键词：

carbon nanotube; carbon nanotube electrode; hydrazine; electrochemistry;

D O I：

10.1016/S0039-9140(02)00318-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Carbon nanotube powder microelectrodes (CNTPMEs) were-used to study the anodic oxidation of hydrazine at Carbon nanotube (CNT)-the novel carbon material. It was found that the electrochemical behaviours were greatly improved at CNTs, indicating that the anodic oxidation could be catalyzed at CNTs. The kinetics parameters of this process were calculated, the heterogeneous electron transfer rate constant k was 0.0019 cm s(-1), (1-alpha)n(alpha) was 0.22. The CNTPMEs were also found with high sensitivity for hydrazine detection, could be used as hydrazine sensors. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：529 / 534

页数：6

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