Nondissociative low-energy electron attachment to SF6, C6F6, C10F8, and c-C7F14:: Negative ion lifetimes

被引:48
作者
Suess, L [1 ]
Parthasarathy, R
Dunning, FB
机构
[1] Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
[2] Rice Univ, Rice Quantum Inst, Houston, TX 77005 USA
关键词
D O I
10.1063/1.1522713
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The lifetimes of long-lived parent anions formed by nondissociative electron attachment to SF6, C6F6, C10F8, and c-C7F14 are investigated. The ions are created via electron transfer in collisions with K(np) Rydberg atoms and their lifetimes determined by observing their decay using a Penning ion trap. The measured lifetimes vary widely from target to target and range from similar to10 mus for C6F6- to similar to10 ms for SF6-. The present results are compared with values obtained in earlier free-electron studies. (C) 2002 American Institute of Physics.
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收藏
页码:11222 / 11227
页数:6
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