Molecular materials from 1,3,2-dithiazolyls. Solid-state structures and magnetic properties of 2,3-naphthalene and quinoxaline derivatives

被引：37

作者：

Barclay, TM

Cordes, AW

George, NA

Haddon, RC

Oakley, RT

Palstra, TTM

Patenaude, GW

Reed, RW

Richardson, JF

Zhang, HZ

机构：

[1] UNIV GUELPH, DEPT CHEM & BIOCHEM, GUELPH, ON N1G 2W1, CANADA

[2] UNIV ARKANSAS, DEPT CHEM & BIOCHEM, FAYETTEVILLE, AR 72701 USA

[3] AT&T BELL LABS, LUCENT TECHNOL, MURRAY HILL, NJ 07974 USA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a700310b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped pi-stack moth; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.

引用

收藏

页码：873 / 874

页数：2

相关论文

共 25 条

[1] ONE-DIMENSIONAL STACKING OF BIFUNCTIONAL DITHIAADIAZOLYL AND DISELENADIAZOLYL RADICALS - PREPARATION AND STRUCTURAL AND ELECTRONIC-PROPERTIES OF 1,3-[(E2N2C)C6H4(CN2E2)] (E = S, SE) [J].

ANDREWS, MP ;

CORDES, AW ;

DOUGLASS, DC ;

FLEMING, RM ;

GLARUM, SH ;

HADDON, RC ;

MARSH, P ;

OAKLEY, RT ;

PALSTRA, TTM ;

SCHNEEMEYER, LF ;

TRUCKS, GW ;

TYCKO, R ;

WASZCZAK, JV ;

YOUNG, KM ;

ZIMMERMAN, NM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3559-3568

[2] THE HIGH-YIELD PREPARATION, CHARACTERIZATION, AND GAS-PHASE STRUCTURE OF THE THERMALLY STABLE CF3CSNSCCF3., 4,5-BIS(TRIFLUOROMETHYL)-1,3,2-DITHIAZOLYL AND THE X-RAY CRYSTAL-STRUCTURE OF BENZO-1,3,2-DITHIAZOLYL [J].

AWERE, EG ;

BURFORD, N ;

MAILER, C ;

PASSMORE, J ;

SCHRIVER, MJ ;

WHITE, PS ;

BANISTER, AJ ;

OBERHAMMER, H ;

SUTCLIFFE, LH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (02) :66-69

[3] X-RAY CRYSTAL-STRUCTURES OF THE 1,3,2-BENZODITHIAZOLYL DIMER AND 1,3,2-BENZODITHIAZOLIUM CHLORIDE SULFUR-DIOXIDE SOLVATE - COMPARISON OF THE MOLECULAR AND ELECTRONIC-STRUCTURES OF THE 10-PI-ELECTRON C6H4S2N+ CATION AND THE C6H4S2N. RADICAL AND DIMER AND A STUDY OF THE VARIABLE-TEMPERATURE MAGNETIC-BEHAVIOR OF THE RADICAL [J].

AWERE, EG ;

BURFORD, N ;

HADDON, RC ;

PARSONS, S ;

PASSMORE, J ;

WASZCZAK, JV ;

WHITE, PS .

INORGANIC CHEMISTRY, 1990, 29 (23) :4821-4830

[4] GENERATION OF UNKNOWN CRYSTAL PHASES FOR AROMATIC-HYDROCARBONS BY PACKING ENERGY CALCULATIONS [J].

BERNSTEIN, J ;

SARMA, JARP ;

GAVEZZOTTI, A .

CHEMICAL PHYSICS LETTERS, 1990, 174 (3-4) :361-368

[5] ORTHO-LITHIOTHIOPHENOL EQUIVALENTS - GENERATION, REACTIONS, AND APPLICATIONS IN SYNTHESIS OF HINDERED THIOLATE LIGANDS [J].

BLOCK, E ;

ESWARAKRISHNAN, V ;

GERNON, M ;

OFORIOKAI, G ;

SAHA, C ;

TANG, K ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :658-665

[6] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[7] TEMPERATURE-DEPENDENCE OF THERMAL MOTION IN CRYSTALLINE NAPHTHALENE [J].

BROCK, CP ;

DUNITZ, JD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG) :2218-2228

[8] TEMPERATURE-DEPENDENCE OF THERMAL MOTION IN CRYSTALLINE ANTHRACENE [J].

BROCK, CP ;

DUNITZ, JD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1990, 46 :795-806

[9] ESR SPECTROSCOPIC INVESTIGATION OF SOME 4-SUBSTITUTED 1,3,2-DITHIAZOLYL AND 2,3,1-DITHIAZOLYL RADICALS [J].

CHUNG, YL ;

FAIRHURST, SA ;

GILLIES, DG ;

PRESTON, KF ;

SUTCLIFFE, LH .

MAGNETIC RESONANCE IN CHEMISTRY, 1992, 30 (07) :666-672

[10]

CORDES AW, 1992, STUD INORG CHEM, V14, P295