Formation of C-C and C-N bonds in NiII ketimide complexes via transient NiIII aryl imides

被引：51

作者：

Bai, Guangcai ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 11期

关键词：

C-C coupling; density functional calculations; imido ligands; nickel; reduction;

D O I：

10.1002/anie.200604547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Has a real nacnac for coupling: Ligand-to-metal electron transfer results from the reactions of the NiI synthon [{(nacnac)-Ni} 2(μ-η3:η3-C6H 5Me)] (nacnac = CH-{CMeN(2,6-iPr2C6H 3)}2) with the azides 2,6-iPr2C 6H3N3 or 2,6-Me2C6H 3N3 to give NiII ketimides (see picture for example; C black, N light blue, Ni white). The reactions proceed via transient NiIII imides, and the differing pathways are directed by the steric demands of the azide substituents. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1856 / 1859

页数：4

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