Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides

被引：7

作者：

Fleming, I ^{[1
]}

Russell, MG ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 02期

关键词：

D O I：

10.1039/b210442c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenyldimethylsilyllithium reacts with several N,N-dimethylamides, and the intermediates, formulated here as successively a carbene and an alpha-silyllithium species, may be trapped with nucleophiles and electrophiles, respectively, although not always with the nucleophile or electrophile of your choice.

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页码：198 / 199

页数：2

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