Controlling photochemistry with distinct hydrophobic nanoenvironments

被引：140

作者：

Kaanumalle, LS

Gibb, CLD

Gibb, BC ^{[1
]}

Ramamurthy, V

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 44期

关键词：

D O I：

10.1021/ja0450197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity. Copyright © 2004 American Chemical Society.

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页码：14366 / 14367

页数：2

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