Non-covalent synthesis in aqueous solution of discrete multi-porphyrin aggregates with programmable stoichiometry and sequence

被引:64
作者
Moschetto, G
Lauceri, R
Gulino, FG
Sciotto, D
Purrello, R
机构
[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy
[2] CNR, IBB, Sez Catania, Catania, Italy
关键词
D O I
10.1021/ja028591b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This unprecedented calixarene templated, noncovalent synthesis of multi-porphyrin complexes in aqueous solution makes it possible to plan the nature, stoichiometry, and sequence of porphyrins. The proposed method presents the same accuracy of the covalent approach and a 100% yield, but it is not as time-consuming as the latter method. Copyright © 2002 American Chemical Society.
引用
收藏
页码:14536 / 14537
页数:2
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