The effect of solvent in the reaction of Cp2ZrH{(μ-H)2BC4H8} with B(C6F5)3:: Formation of [HB(C6F5)3]- salts of the unsupported hydrogen-bridged cation [(μ-H){Cp2Zr(μ-H)2BC4H8}2]+ and the cation [Cp2Zr(OEt2)(OEt)]+

被引：36

作者：

Liu, FC ^{[1
]}

Liu, JP ^{[1
]}

Meyers, EA ^{[1
]}

Shore, SG ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 25期

关键词：

D O I：

10.1021/ja001056w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：6106 / 6107

页数：2

共 15 条

[1] Synthetic, structural and inelastic neutron scattering studies of the hydridobridged cationic complexes [(PMe3)(2)(Y)Pt(mu-H)Pt(Y)(PMe3)(2)](+) (Y=Ph, C6F5, C6Cl5) and of [(PEt3)(2)(H)Pt(mu-H)Pt(Ph)(PEt3)(2)](+) [J].

Albinati, A ;

Chaloupka, S ;

Eckert, J ;

Venanzi, LM ;

Wolfer, MK .

INORGANICA CHIMICA ACTA, 1997, 259 (1-2) :305-316

[2] Structures of transition metal hydrides determined by neutron diffraction [J].

Bau, R ;

Drabnis, MH .

INORGANICA CHIMICA ACTA, 1997, 259 (1-2) :27-50

[3] Cocatalysts for metal-catalyzed olefin polymerization: Activators, activation processes, and structure-activity relationships [J].

Chen, EYX ;

Marks, TJ .

CHEMICAL REVIEWS, 2000, 100 (04) :1391-1434

[4] Organo-Lewis acids as cocatalysts in cationic metallocene polymerization catalysis. Unusual characteristics of sterically encumbered tris(perfluorobiphenyl)borane [J].

Chen, YX ;

Stern, CL ;

Yang, ST ;

Marks, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (49) :12451-12452

[5] Sterically encumbered (perfluoroaryl) borane and aluminate cocatalysts for tuning cation - Anion ion pair structure and reactivity in metallocene polymerization processes. A synthetic, structural, and polymerization study [J].

Chen, YX ;

Metz, MV ;

Li, LT ;

Stern, CL ;

Marks, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (25) :6287-6305

[6] THF RING-OPENING AND H/D EXCHANGE-REACTIONS OF (C5H4ME)2ZR(H)(THF)+ - EVIDENCE FOR HYDROGENOLYSIS OF ZR-CP BONDS [J].

GUO, ZY ;

BRADLEY, PK ;

JORDAN, RF .

ORGANOMETALLICS, 1992, 11 (07) :2690-2693

[7]

GURAM AS, 1995, COMPREHENSIVE ORGA 2, V4, pCH12

[8]

INKROTT KE, 1978, J AM CHEM SOC, V100, P3953

[9] Cyclic hydroborate complexes of metallocenes.: IV.: Weak unsupported single hydrogen bridges in Cp2Zr{(μ-H)B(X)CH2Ph}{(μ-H)2BX} (X = C5H10, C4H8) [J].

Liu, FC ;

Liu, JP ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 1999, 38 (09) :2169-2173

[10]

LIU FC, 1998, THESIS OHIO STATE U

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