Radical stabilizing ability of the ferrocenyl and cyclobutadieneiron tricarbonyl groups

被引：18

作者：

Creary, X ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 14期

关键词：

D O I：

10.1021/ol000119c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

GRAPHICS Computational studies indicate that ferrocenyl substituted methyl radicals owe their stability to a spin delocalization mechanism involving Fe and a major contribution from an eta(4) form, Cyclobutadieneiron tricarbonyl substituted methyl radicals are also calculated to be highly stabilized by spin delocalization onto Fe and a major contribution from an eta(3) form.

引用

页码：2069 / 2072

页数：4

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