Bis-propargylic bis-silanes as precursors of bis(vinylidene)oxanes and -oxepanes

被引：6

作者：

Aubert, P ^{[1
]}

Pornet, J ^{[1
]}

机构：

[1] UNIV POITIERS,LAB SYNTHESE ORGAN,URA 574,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 538卷 / 1-2期

关键词：

propargylsilanes; electrophilic substitution; 3,5-bis(vinylidene)-oxanes; 3,6-bis(vinylidene)oxepanes;

D O I：

10.1016/S0022-328X(97)00061-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of bis-silanes Me3SiCH2-C=C-(CH2)(n)-C=C-CH2SiMe3 (n = 1, 2) is described. These silanes allow one to prepare bis(vinylidene)oxanes when n = 1 and bis(vinylidene)oxepanes when n = 2.

引用

页码：211 / 221

页数：11

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