A metabolomic approach to the evaluation of the origin of extra virgin olive oil: A convenient statistical treatment of mass spectrometric analytical data

被引:41
作者
Cavaliere, Brunella
De Nino, Antonio
Hayet, Fourati
Lazez, Aida
Macchione, Barbara
Moncef, Cossentini
Perri, Enzo
Sindona, Giovanni
Tagarelli, Antonio
机构
[1] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata Di Rende, CS, Italy
[2] Inst Olivier, Sfax 3029, Tunisia
[3] Ist Sperimentale Olivicoltura, CRA, I-87036 Arcavacata Di Rende, Italy
[4] Inst Preparatoire Etud Ingn Sfax, Sfax 3000, Tunisia
关键词
olive oil; metabolomics; lipoxygenase pathway; traceability; GC-CI-ITD; SPME analysis; statistical analysis;
D O I
10.1021/jf062929u
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The selection of suitable markers from the secondary metabolism of lipoxygenase, in experimental olive oils produced from drupes harvested in different areas of the Italian Calabria region and of Tunisia, allows an easy discrimination between each cluster of samples. The origin of the foodstuff can be ascertained even when the distances between the production zones are very close to each other as in Calabria. Olive oils produced from irrigated and nonirrigated farms in Tunisia were also clearly distinguishable. The markers were detected by chemical ionization mass spectrometry with an ion trap gas chromatography-mass spectrometry apparatus. The quantitative data of Calabrian olive oil samples were subjected to linear discriminant analysis, whereas the Tunisian data were treated by means of other two statistical tools, i.e., the Kruskal-Wallis test and the Wald-Wolfowitz test.
引用
收藏
页码:1454 / 1462
页数:9
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