Self-assembled one-dimensional arrays of gold-dendron nanocomposites

被引:32
作者
Nakao, S
Torigoe, K
Kon-No, K
Yonezawa, T
机构
[1] Tokyo Univ Sci, Dept Ind Chem, Shinjuku Ku, Tokyo 1628601, Japan
[2] Tokyo Univ Sci, Inst Colloid & Interface Sci, Shinjuku Ku, Tokyo 1628601, Japan
[3] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[4] PRESTO, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
D O I
10.1021/jp021710p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gold-dendron nanocomposites have been prepared by using poly(oxymethylphenylene) dendrons (PPD) of generations (G) 1 -4 functionalized with a thiol group at the focal point as capping ligands. The mean, particle size was 1.5 and 1.4 nm for G1 and G2, respectively, with 12 and 18% of relative standard deviation, and the particle size increased for higher generations with a remarkable broadening of the size distribution. For G1 and G2, spontaneous formation of one-dimensional arrays has been reproducibly observed on carbon film, with 2.5 and 2.3 nm of line spacing for G1 and G2, respectively.
引用
收藏
页码:12097 / 12100
页数:4
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