Solid Catalysts for the Selective Low-Temperature Oxidation of Methane to Methanol

被引：466

作者：

Palkovits, Regina ^{[1
]}

Antonietti, Markus ^{[2
]}

Kuhn, Pierre ^{[2
]}

Thomas, Arne ^{[2
]}

Schueth, Ferdi ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[2] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 37期

关键词：

methane; methanol; oxidation; Periana catalyst; triazines; ACTIVATION; CONVERSION; GOLD;

D O I：

10.1002/anie.200902009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Again and again and again: The title reaction was achieved on a solid catalyst in a covalent triazine-based framework formed by trimerization of 2,6-dicyanopyridine in a ZnCl2 melt. The material possesses bipyridine units as coordination sites for platinum. It shows high activity and can be separated easily from the reaction mixture and recycled several times without significant loss of activity. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6909 / 6912

页数：4

共 30 条

[1]

AXELROD MG, 1994, NATURAL GAS CONVERSI, V2, P93

[2]

Baerns M., 1992, Perspectives in Catalysis

[3] Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons [J].

Conley, Brian L. ;

Tenn, William J., III ;

Young, Kenneth J. H. ;

Ganesh, Somesh K. ;

Meier, Steven K. ;

Ziatdinov, Vadim R. ;

Mironov, Oleg ;

Oxgaard, Jonas ;

Gonzales, Jason ;

Goddard, William A., III ;

Periana, Roy A. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 251 (1-2) :8-23

[4] ASPECTS OF METHANE CHEMISTRY [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1995, 95 (04) :987-1007

[5] Gold redox catalysis for selective oxidation of methane to methanol [J].

De Vos, DE ;

Sels, BE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (01) :30-32

[6] RARE-EARTHS AS CATALYSTS FOR THE OXIDATIVE COUPLING OF METHANE TO ETHYLENE [J].

FORLANI, O ;

ROSSINI, S .

MATERIALS CHEMISTRY AND PHYSICS, 1992, 31 (1-2) :155-158

[7]

GESSER HD, 1992, METHANE CONVERSION O, P403

[8]

Henry P M, 1980, PALLADIUM CATALYZED

[9]

Jones C. J., 2004, ANGEW CHEM, V116, P4726, DOI DOI 10.1002/ANGE.200461055

[10] Selective oxidation of methane to methanol catalyzed, with C-H activation, by homogeneous, cationic gold [J].

Jones, CJ ;

Taube, D ;

Ziatdinov, VR ;

Periana, RA ;

Nielsen, RJ ;

Oxgaard, J ;

Goddard, WA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (35) :4626-4629

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