Synthesis of novel organoboron polymers by hydroboration polymerization of bisallene compounds

被引：30

作者：

Matsumi, N ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DEPT POLYMER CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

POLYMER BULLETIN | 1997年 / 38卷 / 05期

关键词：

D O I：

10.1007/s002890050083

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper describes synthesis of novel organoboron polymers by hydroboration polymerization of bisallene compounds. The polymers were prepared by polyaddition between thexylborane and bisallenes. The polymers obtained have allylborane units in their main chains and can be expected as a novel type of reactive polymers. The polymer was subjected to a chain transformation reaction and the corresponding polyalcohol was obtained. Hydroboration polymerization of bisallene with mesitylborane was also carried out. It was found that the polymer prepared from mesitylborane showed higher stability than that prepared from thexylborane.

引用

页码：531 / 536

页数：6

共 14 条

[1]

CHUJO Y, 1991, POLYM BULL, V25, P1

[2] HYDROBORATION POLYMERIZATION OF DICYANO COMPOUNDS .3. SYNTHESIS OF POLY(CYCLODIBORAZANE)S BY THE REACTION OF ALPHA,OMEGA-DICYANOALKANES WITH THEXYLBORANE [J].

CHUJO, Y ;

TOMITA, I ;

SAEGUSA, T .

POLYMER BULLETIN, 1993, 31 (05) :553-558

[3] HYDROBORATION POLYMERIZATION OF DICYANO COMPOUNDS .4. SYNTHESIS OF STABLE POLY(CYCLODIBORAZANE)S FROM DIALKYLBORANES [J].

CHUJO, Y ;

TOMITA, I ;

SAEGUSA, T .

MACROMOLECULES, 1994, 27 (23) :6714-6717

[4] HYDROBORATION POLYMERIZATION OF DICYANO COMPOUNDS .2. REACTIONS OF ISOPHTHALONITRILE WITH PRIMARY OR SECONDARY ALKYLBORANE [J].

CHUJO, Y ;

TOMITA, I ;

SAEGUSA, T .

POLYMER BULLETIN, 1993, 31 (05) :547-552

[5] VERSATILE REACTIONS OF ORGANOBORON POLYMERS PREPARED BY HYDROBORATION POLYMERIZATION [J].

CHUJO, Y .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1994, A31 (11) :1647-1655

[6] REACTIONS OF ORGANOBORON POLYMERS PREPARED BY HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF POLY(ALCOHOL) BY REACTION WITH CARBON-MONOXIDE [J].

CHUJO, Y ;

TOMITA, I ;

HASHIGUCHI, Y ;

SAEGUSA, T .

MACROMOLECULES, 1991, 24 (10) :3010-3012

[7] REACTIONS OF ORGANOBORON POLYMERS PREPARED BY HYDROBORATION POLYMERIZATION .3. SYNTHESIS OF POLY(ALCOHOL)S BY THE REACTION WITH ALPHA,ALPHA-DICHLOROMETHYL METHYL-ETHER [J].

CHUJO, Y ;

TOMITA, I ;

SAEGUSA, T .

POLYMER BULLETIN, 1991, 26 (02) :165-168

[8] HYDROBORATION POLYMERIZATION OF DICYANO COMPOUNDS .1. SYNTHESIS OF BORON-CONTAINING POLYMERS BY THE REACTION BETWEEN T-BUBH2.NME3 AND DICYANO COMPOUNDS [J].

CHUJO, Y ;

TOMITA, I ;

MURATA, N ;

MAUERMANN, H ;

SAEGUSA, T .

MACROMOLECULES, 1992, 25 (01) :27-32

[9] HYDROBORATION POLYMERIZATION .2. SYNTHESIS OF ORGANOBORON POLYMERS BY THE REACTION BETWEEN DIYNE AND THEXYLBORANE [J].

CHUJO, Y ;

TOMITA, I ;

HASHIGUCHI, Y ;

SAEGUSA, T .

MACROMOLECULES, 1992, 25 (01) :33-36

[10] HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF ORGANOBORON POLYMERS BY POLYADDITION BETWEEN DIENE AND MONOALKYLBORANE [J].

CHUJO, Y ;

TOMITA, I ;

HASHIGUCHI, Y ;

TANIGAWA, H ;

IHARA, E ;

SAEGUSA, T .

MACROMOLECULES, 1991, 24 (02) :345-348

← 1 2 →