The configurational assignment of the optically active 5-(1-hydroperoxyethyl)-3-ethoxycarbonyl-2-methylfuran and its alcohol by exciton-coupled circular dichroism (ECCD)

被引：11

作者：

Adam, W ^{[1
]}

Humpf, HU ^{[1
]}

Korb, MN ^{[1
]}

Schreier, P ^{[1
]}

机构：

[1] UNIV WURZBURG,INST FOOD CHEM,D-97074 WURZBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 21期

关键词：

D O I：

10.1016/S0957-4166(97)00515-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The absolute configuration of the furan-derived hydroperoxide land its alcohol 2, readily available in optically active form by kinetic resolution of the racemic hydroperoxide with horseradish peroxidase (HRP), was determined by the exciton-coupled circular dichroism (ECCD) method on their 2-naphthoate derivatives 4. (C) 1997 Elsevier Science Ltd.

引用

页码：3555 / 3558

页数：4

共 11 条

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Korb, MN
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[3] EXCITON CHIRALITY METHOD FOR ESTABLISHING ABSOLUTE-CONFIGURATION OF 2-FURYLCARBINOLS
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[4] A new exciton-coupled circular dichroism method for assigning the absolute configuration in acyclic alpha- and beta-hydroxy carboxylic acids
Gimple, O
Schreier, P
Humpf, HU
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (01) : 11 - 14
[5] Harada N., 1983, CIRCULAR DICHROIC SP
[6] Hoch U, 1997, CHIRALITY, V9, P69, DOI 10.1002/(SICI)1520-636X(1997)9:1<69::AID-CHIR13>3.0.CO
[7] 2-O
[8] Reactivity of furylhydroperoxides in asymmetric oxidation and kinetic resolution
Lattanzi, A
Bonadies, F
Scettri, A
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (13) : 2141 - 2151
[9] Nakanishi K., 1994, CIRCULAR DICHROISM P
[10] Asymmetric oxidation with furylhydroperoxides
Scettri, A
Bonadies, F
Lattanzi, A
[J]. TETRAHEDRON-ASYMMETRY, 1996, 7 (03) : 629 - 632

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