Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

被引：61

作者：

Askarizadeh, Elham ^{[1
,2
]}

Yaghoob, Sahar Bani ^{[1
,2
]}

Boghaei, Davar M. ^{[2
]}

Slawin, Alexandra M. Z. ^{[3
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, EaStCHEM, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

PORPHYRIN-CORROLE DYADS; O BOND ACTIVATION; HANGMAN PORPHYRINS; FUEL-CELLS; OXYGEN; REACTIVITY; WATER; O-2; ARCHITECTURES; COBALT(III);

D O I：

10.1039/b923189g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.

引用

页码：710 / 712

页数：3

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