Equilibrium studies on reactive extraction of succinic acid from aqueous solutions with tertiary amines

被引:41
作者
Hong, YK [1 ]
Hong, WH [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem Engn, Taejon 305701, South Korea
关键词
D O I
10.1007/s004499900090
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Reactive extraction of succinic acid from aqueous solutions with various tertiary amines dissolved in 1-octanol and n-heptane has been studied as a function of the acid concentration and the chain length of tertiary amine. When 1-octanol was used as diluent, the extractability of the tertiary amine was proportional to the chain length of tertiary amine at the same concentration of amines. The loading values were also proportional to the chain length of tertiary amine. However, when n-heptane was used as diluent, the extractability and loading values of the tertiary amine were inversely proportional to the chain length of amines. It was due to the aggregate formation of the acid-amine complex.
引用
收藏
页码:477 / 481
页数:5
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