MOF-Graphite Oxide Composites: Combining the Uniqueness of Graphene Layers and Metal-Organic Frameworks

被引:569
作者
Petit, Camille
Bandosz, Teresa J. [1 ]
机构
[1] CUNY City Coll, Dept Chem, New York, NY 10031 USA
基金
美国国家科学基金会;
关键词
PORE-SIZE; DESIGN; ADSORPTION; AMMONIA; FLEXIBILITY; ADSORBENTS; DYNAMICS; SORPTION; STORAGE; WATER;
D O I
10.1002/adma.200901581
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanocomposites containing graphite oxide (GO) and metal-organic frameworks (MOFs) are prepared. They have a well-defined structure, in which graphene layers from GO alternate with layers of MOF via linkages between epoxy groups from Go and zinc oxide from the MOF (see image). The enhanced porosity and dispersive forces of the composites compared to the precursors provide views for applications in gas adsorption.
引用
收藏
页码:4753 / +
页数:6
相关论文
共 37 条
  • [1] Metal-organic frameworks with high capacity and selectivity for harmful gases
    Britt, David
    Tranchemontagne, David
    Yaghi, Omar M.
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (33) : 11623 - 11627
  • [2] Brodie B., 1860, ANN CHIM PHYS, V59, P466
  • [3] Water dynamics in graphite oxide investigated with neutron scattering
    Buchsteiner, Alexandra
    Lerf, Anton
    Pieper, Joerg
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (45) : 22328 - 22338
  • [4] Selective gas sorption within a dynamic metal-organic framework
    Chen, Banglin
    Ma, Shengqian
    Hurtado, Eric J.
    Lobkovsky, Emil B.
    Liang, Chengdu
    Zhu, Haoguo
    Dai, Sheng
    [J]. INORGANIC CHEMISTRY, 2007, 46 (21) : 8705 - 8709
  • [5] Preparation and characterization of graphene oxide paper
    Dikin, Dmitriy A.
    Stankovich, Sasha
    Zimney, Eric J.
    Piner, Richard D.
    Dommett, Geoffrey H. B.
    Evmenenko, Guennadi
    Nguyen, SonBinh T.
    Ruoff, Rodney S.
    [J]. NATURE, 2007, 448 (7152) : 457 - 460
  • [6] Highly porous and stable metal-organic frameworks: Structure design and sorption properties
    Eddaoudi, M
    Li, HL
    Yaghi, OM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) : 1391 - 1397
  • [7] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [8] The interaction of water with MOF-5 simulated by molecular dynamics
    Greathouse, Jeffery A.
    Allendorf, Mark D.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (33) : 10678 - 10679
  • [9] Tailoring the dimensionality of metal-organic frameworks incorporating Pt and Pd. From molecular complexes to 3D networks
    Hafizovic, Jasmina
    Krivokapic, Alexander
    Szeto, Kai C.
    Jakobsen, Soren
    Lillerud, Karl Petter
    Olsbye, Unni
    Tilset, Mats
    [J]. CRYSTAL GROWTH & DESIGN, 2007, 7 (11) : 2302 - 2304
  • [10] The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities
    Hafizovic, Jasmina
    Bjorgen, Morten
    Olsbye, Unni
    Dietzel, Pascal D. C.
    Bordiga, Silvia
    Prestipino, Carmelo
    Lamberti, Carlo
    Lillerud, Karl Petter
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) : 3612 - 3620