Size-selective olefin hydrogenation by a Pd nanocluster provided in an apo-ferritin cage

被引：281

作者：

Ueno, T ^{[1
]}

Suzuki, M

Goto, T

Matsumoto, T

Nagayama, K

Watanabe, Y

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan

[3] Nagoya Univ, Grad Sch Sci, Dept Phys, Nagoya, Aichi 4648602, Japan

[4] Natl Inst Physiol Sci, Okazaki, Aichi 4448585, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 19期

关键词：

hydrogenation; nanoparticles; palladium; proteins; supramolecular chemistry;

D O I：

10.1002/anie.200353436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deep penetration by substrates through the size-restricted channels of an apoferritin cage results in size-selective olefin hydrogenation at the Pd nanocluster core (see picture). The encapsulated zero-valent cluster is synthesized in situ by chemical reduction of PdII ions in the apoferritin cage.

引用

页码：2527 / 2530

页数：4

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