Helical conjugated polymers by design

被引：12

作者：

Dubus, S ^{[1
]}

Marceau, V ^{[1
]}

Leclerc, M ^{[1
]}

机构：

[1] Univ Laval, Ctr Rech Sci & Ingn Macromol, Dept Chim, Canada Res Chair Electract & Photoact Polymers, Quebec City, PQ G1K 7P4, Canada

来源：

MACROMOLECULES | 2002年 / 35卷 / 25期

关键词：

D O I：

10.1021/ma021250y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Some alternating phenylene-furan units can lead to conformationally locked conjugated polymers. Depending upon the substitution pattern, rigid-rod-like or helical structures can be rationally designed. The presence of helical structure in poly(1,4-(2,3-dialkoxyphenylene)-alt-2,5-furan)s has been demonstrated by adding chiral side chains and by performing circular dichroism measurements. In a good solvent, this polymer exhibits some chiroptical properties which decreases upon aggregation in poor solvents. In contrast, rigid-rod-like poly(1,4-(2,5-di-(S)-2-methylbutoxyphenylene)-alt-2,5-furan) only shows chiroptical properties upon aggregation.

引用

页码：9296 / 9299

页数：4

共 41 条

[1] Chirality in regioregular and soluble polythiophene: An internal probe of conformational changes induced by minute solvation variation [J].

Bidan, G ;

Guillerez, S ;

Sorokin, V .

ADVANCED MATERIALS, 1996, 8 (02) :157-&

[2] Molecular design and characterization of chromic polyfluorene derivatives [J].

Blondin, P ;

Bouchard, J ;

Beaupré, S ;

Belletête, M ;

Durocher, G ;

Leclerc, M .

MACROMOLECULES, 2000, 33 (16) :5874-5879

[3] CHIROPTICAL PROPERTIES OF REGIOREGULAR CHIRAL POLYTHIOPHENES [J].

BOUMAN, MM ;

HAVINGA, EE ;

JANSSEN, RAJ ;

MEIJER, EW .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 256 :439-448

[4] Self-assembly of folded m-phenylene ethynylene oligomers into helical columns [J].

Brunsveld, L ;

Meijer, EW ;

Prince, RB ;

Moore, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :7978-7984

[5] Highly ordered structures of amphiphilic polythiophenes in aqueous media [J].

Brustolin, F ;

Goldoni, F ;

Meijer, EW ;

Sommerdijk, NAJM .

MACROMOLECULES, 2002, 35 (03) :1054-1059

[6] OPTICALLY-ACTIVE POLYMERS OF 1-ALKYNES [J].

CIARDELLI, F ;

LANZILLO, S ;

PIERONI, O .

MACROMOLECULES, 1974, 7 (02) :174-179

[7] Intermolecular interactions in conjugated oligothiophenes.: 3.: Optical and photophysical properties of quaterthiophene and substituted quaterthiophenes in various environments [J].

DiCésare, N ;

Belletête, M ;

Garcia, ER ;

Leclerc, M ;

Durocher, G .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (20) :3864-3875

[8] Intermolecular interactions in conjugated oligothiophenes.: 2.: Quantum chemical calculations performed on crystalline structures of terthiophene and substituted terthiophenes [J].

DiCésare, N ;

Belletête, M ;

Leclerc, M ;

Durocher, G .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (07) :803-811

[9] Intermolecular interactions in conjugated oligothiophenes.: 1.: Optical spectra of terthiophene and substituted terthiophenes recorded in various environments [J].

DiCésare, N ;

Belletête, M ;

Marrano, C ;

Leclerc, M ;

Durocher, G .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (07) :795-802

[10] Thermochromic and solvatochromic conjugated polymers by design [J].

Dufresne, G ;

Bouchard, J ;

Belletête, M ;

Durocher, G ;

Leclerc, M .

MACROMOLECULES, 2000, 33 (22) :8252-8257

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