A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units

被引：173

作者：

Tong, ML

Li, LJ

Mochizuki, K

Chang, HC

Chen, XM

Li, Y

Kitagawa, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[3] Lanzhou Univ, Inst Organ Chem, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 03期

关键词：

D O I：

10.1039/b210914j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel three-dimensional coordination polymer with a mixed-valence localized copper(I, II) dimeric unit, [Cu-2(4-pya) (3)](n) (4-pya = 4-pyridinecarboxylate), was hydrothermally synthesized via a simultaneous in-situa redox and hydrolysis reaction of Cu(II) and 4-cyanopyridine and crystallographically characterized to be a twofold interpenetrated three-dimensional coordination network with a cubic [Cu-16(4-pya)(12)] building unit.

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收藏

页码：428 / 429

页数：2

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