A hexacarbene complex derived from 1,1′-methylenebis(4-butyl-1H-1,2,4-triazolium) diiodide.: Synthesis, characterization and catalytic activity

被引：19

作者：

Díez-Barra, E ^{[1
]}

Guerra, J ^{[1
]}

Rodríguez-Curiel, RI ^{[1
]}

Merino, S ^{[1
]}

Tejeda, J ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Quim, Ciudad Real, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 660卷 / 01期

关键词：

1,2,4-triazole-5-ylidene; carbene; palladium; catalysis;

D O I：

10.1016/S0022-328X(02)01730-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a hexacarbene complex (1) derived from 1,1'-methylenebis(4-butyl-1H-1,2,4-triazolium) diiodide are reported. The organic backbone was constructed prior to the introduction of metal atoms by reaction with palladium(II) acetate. The catalytic activity of 1 in a Heck reaction has been tested. (C) 2002 Elsevier Science B. V. All rights reserved.

引用

页码：50 / 54

页数：5

共 37 条

[31]

Schwarz J, 2000, CHEM-EUR J, V6, P1773, DOI 10.1002/(SICI)1521-3765(20000515)6:10<1773::AID-CHEM1773>3.0.CO

[32]

2-P

[33] Evaluation of ruthenium-based complexes for the controlled radical polymerization of vinyl monomers [J].

Simal, F ;

Jan, D ;

Delaude, L ;

Demonceau, A ;

Spirlet, MR ;

Noels, AF .

CANADIAN JOURNAL OF CHEMISTRY, 2001, 79 (5-6) :529-535

[34]

TAYLOR EC, 1997, SYNTHESIS-STUTTGART, P467

[35] The development of L2X2Ru=CHR olefin metathesis catalysts:: An organometallic success story [J].

Trnka, TM ;

Grubbs, RH .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (01) :18-29

[36] GEMINAL POLY(1-PYRAZOLYL)ALKANES AND THEIR COORDINATION CHEMISTRY [J].

TROFIMENKO, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (17) :5118-+

[37] SYNTHESIS OF DENDRITIC POLYAMIDES VIA A CONVERGENT GROWTH APPROACH [J].

UHRICH, KE ;

FRECHET, JMJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (13) :1623-1630

← 1 2 3 4 →