Different effects of cerium ions doping on properties of anatase and rutile TiO2

被引:81
作者
Li, Guangqin
Liu, Chunyan [1 ]
Liu, Yun
机构
[1] Chinese Acad Sci, Lab Organ Optoelect Funct Mat & Mol Engn, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
cerium ions; doping; anatase; rutile; TiO2;
D O I
10.1016/j.apsusc.2006.05.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pure and Ce4+ doped anatase and rutile TiO2 were prepared by hydrothermal methods and characterized by XRD, TEM, UV-vis diffusion spectroscopy, and XPS measurements. The photocatalytic reactivity of the catalysts was evaluated by the photodegradation of Rhodamine B (RB) under ultraviolet irradiation. The photocatalytic efficiency of the rutile sample doped with an appropriate amount of Ce4+ was enhanced while all Ce4+ doped anatase samples showed a much lower activity than pure anatase. The reasons were discussed (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2481 / 2486
页数:6
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