Synthesis, structures, and reactivities of rhodium and ruthenium complexes with a novel chiral cyclopentadienyl-ferrocenyldiphenylphosphine bidentate ligand

被引：48

作者：

Nishibayashi, Y ^{[1
]}

Takei, I ^{[1
]}

Hidai, M ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT CHEM & BIOTECHNOL,GRAD SCH ENGN,HONGO,TOKYO 113,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 14期

关键词：

D O I：

10.1021/om9702385

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel rhodium(I) and ruthenium(II) complexes with the chiral cyclopentadienyl-phosphine bidentate ligand PPFCp have been prepared and characterized crystallographically. The cationic ruthenium-vinylidene complex [Ru(C=CHPh)(PPh3)(PPFCp)]PF6, obtained from [RuCl(PPh3)(PPFCp)] and phenylacetylene, reacts with 1-buten-3-ol to afford 3-methyl-1-phenyl-4-penten-2-one in moderate yield with moderate enantioselectivity.

引用

页码：3091 / 3093

页数：3

共 39 条

[1]

[Anonymous], ANGEW CHEM INT EDIT

[2]

[Anonymous], ADV ORGANOMET CHEM

[3]

Brunner H., 1993, HDB ENANTIOSELECTIVE

[4] SYNTHESIS, CRYSTAL-STRUCTURE AND ABSOLUTE-CONFIGURATION OF THE MENTHYLCYCLOPENTADIENYL COMPLEX OF RUTHENIUM (+)578-ETA-5-MCP)RU(CO)P(C6H5)3C1 [J].

CESAROTTI, E ;

CIANI, G ;

SIRONI, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 216 (01) :87-95

[5] HALF-SANDWICH CHIRAL RUTHENIUM COMPLEXES [J].

CONSIGLIO, G ;

MORANDINI, F .

CHEMICAL REVIEWS, 1987, 87 (04) :761-778

[6]

GOKEL GW, 1972, J ORG CHEM, V37, P3052, DOI 10.1021/jo00985a002

[7] SYNTHESIS AND APPLICATIONS OF CHIRAL CYCLOPENTADIENYLMETAL COMPLEXES [J].

HALTERMAN, RL .

CHEMICAL REVIEWS, 1992, 92 (05) :965-994

[8] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL-COMPLEXES .1. PREPARATION OF CHIRAL FERROCENYLPHOSPHINES [J].

HAYASHI, T ;

MISE, T ;

FUKUSHIMA, M ;

KAGOTANI, M ;

NAGASHIMA, N ;

HAMADA, Y ;

MATSUMOTO, A ;

KAWAKAMI, S ;

KONISHI, M ;

YAMAMOTO, K ;

KUMADA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (04) :1138-1151

[9]

Helmchen G., 1995, STEREOSELECTIVE SYNT

[10] Highly enantioselective catalytic Pauson-Khand type formation of bicyclic cyclopentenones [J].

Hicks, FA ;

Buchwald, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (46) :11688-11689

← 1 2 3 4 →