Hydrothermal synthesis and crystal structure of the new manganese(II) thioantimonate(III), Mn(en)(3)Sb4S7

被引:67
作者
Bensch, W
Schur, M
机构
[1] Inst. für Anorganische Chemie, Universität Frankfurt, D-60439-Frankfurt a.M.
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 03期
关键词
thioantimonates; hydrothermal synthesis; crystal structure;
D O I
10.1515/znb-1997-0318
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of manganese with antimony and sulfur in an aqueous ethylenediamine ten) solution under hydrothermal conditions gives Mn(en)(3)Sb4S7. The structure of the title compound consists of Mn(en)(3)(2+) cations and infinite one-dimensional (Sb4S72-)n anions forming slabs via long secondary interchain Sb...S bonds. A comparison between phases with polymeric (Sb4S72-)(n) anions shows in general a trend towards a lower dimensionality of the thioantimonate assembly with increasing cation size. In the title compound the lowest number of interchain Sb...S interactions is observed among other phases with chainlike Sb4S72- anions.
引用
收藏
页码:405 / 409
页数:5
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