Thermodynamic studies of mixed aqueous solutions of binary electrolytes of Na2SO4 and K2SO4

被引:5
作者
Sirbu, R [1 ]
机构
[1] Ovidius Univ Constantza, Dept Chem, Constantza 8700, Romania
关键词
excess Gibbs energy; ionic activity coefficient; NaSO4/K2SO4 binary aqueous solution; ternary aqueous solution;
D O I
10.1016/S0040-6031(99)00429-3
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermodynamic study of Na2SO4 and K2SO4 binary and ternary aqueous solutions is materialized in obtaining both average ionic activity coefficients and excess Gibbs energies, from cryometric data. Differential cryometric method utilized for obtaining experimental data has permitted the measurement of cryometric effect with a precision of +/-2 x 10(-4) K. The experimental data process has been obtained using a specific calculation program. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1 / 10
页数:10
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