Synthesis of nanostructured polymer-titanium oxide composites through the assembly of titanium-oxo clusters and amphiphilic block copolymers micelles

被引：37

作者：

Steunou, N

Förster, S

Florian, P

Sanchez, C

Antonietti, M

机构：

[1] Univ Paris 06, CNRS, UMR 7574, F-75252 Paris 05, France

[2] Max Planck Inst Kolloid & Grenzflachenforsch, D-14424 Potsdam, Germany

[3] Ctr Rech Mat Haute Temp 1D, F-45071 Orleans 2, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 12期

关键词：

D O I：

10.1039/b203566a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The titanium oxo-organo clusters [Ti16O16 (OEt)(32)] are used as precondensed building blocks for the sol-gel synthesis of titanium oxide nanostructures in the presence of an amphiphilic block copolymer PS-b-PMAA (PS = polystyrene block; PMAA = polymethacrylic acid block) as a structure directing agent. It is shown that clusters-opposite to the more reactive titanium alkoxides-can be organized and hydrolysed under controlled conditions. The resulting polymer-titanium oxide nanocomposites were characterised by TEM, SAXS, O-17 MAS NMR spectroscopy.

引用

页码：3426 / 3430

页数：5

共 32 条

[1] Structural characterization of titanium-oxo-polymers synthesized in the presence of protons or complexing ligands as inhibitors [J].