Study on the electrochemical characteristics of quasi-solid-state electric double layer capacitors assembled with sulfonated poly(ether ether ketone)

被引:12
作者
Kim, Dong-Won
Ko, Jang Myoun
Kim, Wan Ju
Kim, Jong Huy
机构
[1] Hanbat Natl Univ, Dept Appl Chem, Taejon 305719, South Korea
[2] Korea Inst Energy Res, Energy Storage Res Ctr, Taejon 305343, South Korea
关键词
electric double layer capacitors; electrochemical characteristics; polymer electrolyte; proton exchange membrane; sulfonated poly(ether ether ketone);
D O I
10.1016/j.jpowsour.2005.12.059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sulfonated poly(ether ether ketone) (S-PEEK) was synthesized by sulfonation of commercial PEEK. The S-PEEK membrane was prepared by casting from organic solution dissolving the polymer, and the polymer electrolyte was obtained by soaking the S-PEEK membrane in water or sulfuric acid solution. The effect of soaking solvent on the liquid uptake and the ionic conductivity of the polymer electrolyte has been investigated. The quasi-solid- state electric double layer capacitors (EDLCs) which consisted of activated carbon electrodes and polymer electrolyte were assembled, and their electrochemical characteristics were studied by cyclic voltammetry and charge-discharge cycle tests. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:300 / 303
页数:4
相关论文
共 12 条
[1]  
Eisenberg A., 1982, ACS S SERIES, V180
[2]   Supercapacitor based on activated carbon and polyethylene oxide-KOH-H2O polymer electrolyte [J].
Lewandowski, A ;
Zajder, M ;
Frackowiak, E ;
Béguin, F .
ELECTROCHIMICA ACTA, 2001, 46 (18) :2777-2780
[3]   Evaluation of nafion based double layer capacitors by electrochemical impedance spectroscopy [J].
Lufrano, F ;
Staiti, P ;
Minutoli, M .
JOURNAL OF POWER SOURCES, 2003, 124 (01) :314-320
[4]  
MATSUDA Y, 1993, J ELECTROCHEM SOC, V140, P109
[5]   An electrochemical double layer capacitor using an activated carbon electrode with gel electrolyte binder [J].
Osaka, T ;
Liu, XJ ;
Nojima, M ;
Momma, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (05) :1724-1729
[6]   All-solid-state supercapacitor using a Nafion® polymer membrane and its hybridization with a direct methanol fuel cell [J].
Park, KW ;
Ahn, HJ ;
Sung, YE .
JOURNAL OF POWER SOURCES, 2002, 109 (02) :500-506
[7]   Thermal stability of Nafion(R) in simulated fuel cell environments [J].
Samms, SR ;
Wasmus, S ;
Savinell, RF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (05) :1498-1504
[8]   All-solid supercapacitor based on polyaniline and sulfonated poly(ether ether ketone) [J].
Sivaraman, P ;
Hande, VR ;
Mishra, VS ;
Rao, CS ;
Samui, AB .
JOURNAL OF POWER SOURCES, 2003, 124 (01) :351-354
[9]   All solid electric double layer capacitors based on Nafion ionomer [J].
Staiti, P ;
Minutoli, M ;
Lufrano, F .
ELECTROCHIMICA ACTA, 2002, 47 (17) :2795-2800
[10]   Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes [J].
Xing, PX ;
Robertson, GP ;
Guiver, MD ;
Mikhailenko, SD ;
Wang, KP ;
Kaliaguine, S .
JOURNAL OF MEMBRANE SCIENCE, 2004, 229 (1-2) :95-106