Copper-catalysed intramolecular O-H addition to unactivated alkenes

被引：41

作者：

Adrio, Luis A. ^{[1
]}

Quek, Louisa Shuyi ^{[1
]}

Taylor, Jason G. ^{[1
]}

Hii, King Kuok ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

TETRAHEDRON | 2009年 / 65卷 / 50期

基金：

英国工程与自然科学研究理事会;

关键词：

CARBOXYLIC-ACIDS; TRIFLIC ACID; GAMMA-HYDROXY; HYDROALKOXYLATION; OLEFINS; ALCOHOLS; CYCLOISOMERIZATION; HYDROAMINATION; LACTONIZATION; BONDS;

D O I：

10.1016/j.tet.2009.10.055

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular cyclisation of omega-alkenoic acids and alkenols can be achieved using a catalytic amount of Cu(OTf)(2) to afford lactones and cyclic ethers, offering a practical alternative to existing catalysts. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：10334 / 10338

页数：5

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