Photocatalytic overall water splitting with dual-bed system under visible light irradiation

被引：48

作者：

Bae, Sang Won ^{[1
]}

Ji, Sang Min ^{[1
]}

Hong, Suk Joon ^{[1
]}

Jang, Ji Wook ^{[1
]}

Lee, Jae Sung ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Ecofriendly Catalysis & Energy Lab, Pohang 790784, South Korea

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2009年 / 34卷 / 08期

关键词：

Photocatalysts; Water splitting; Dual-bed system; WO3; Rh-doped SrTiO3; OXIDATION; MEDIATOR; HYDROGEN; O-2; H-2;

D O I：

10.1016/j.ijhydene.2009.02.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic overall water splitting has been demonstrated with WO3 for oxygen producing photocatalyst (OPC), and Rh-doped SrTiO3 for hydrogen producing photocatalyst (HPC) in a simulated dual-bed system under visible light irradiation (lambda >= 400 nm). The Fe3+/Fe Fe2+ redox couple was chosen as the most effective electron mediator between OPC and HPC. The overall performance of the dual-bed system was limited by the low activity of HPC, and thus the activity of HPC should be increased to improve the overall performance. For overall water splitting reaction in a dual-bed system, the conduction band of OPC must be more negative than the redox potential of the electron acceptors and the valence band of HPC must be more positive than the redox potential of the electron donors. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：3243 / 3249

页数：7

共 22 条

[1] PHOTOCHEMICAL PRODUCTION OF HYDROGEN AND OXYGEN FROM WATER - A REVIEW AND STATE-OF-THE-ART [J].