Preparation of organic metal nanocrystals in polymer matrix

被引：6

作者：

Jeszka, JK

Tracz, A

Wostek, D

Boiteux, G

Kryszewski, M

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

[2] Tech Univ Lodz, Dept Mol Phys, PL-90924 Lodz, Poland

[3] Univ Lyon 1, CNRS, LMPB, UMR 5627, F-69622 Villeurbanne, France

来源：

SYNTHETIC METALS | 2000年 / 109卷 / 1-3期

关键词：

nanocrystals; ET2I3; UV-Vis; IR; AFM; Raman; X-ray diffraction; polymer matrix;

D O I：

10.1016/S0379-6779(99)00221-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanocrystals of bis(ethylenedithio)tetrathiafulvalene (ET) polyiodides in polymer matrices were obtained using different methods of crystallisation under limited diffusion conditions. Broadening X-ray diffraction (MID) lines and atomic force microscopy (AFM) confirm the decreasing size of the crystals. The positions of the W-Vis absorption maxims are practically the same; IR peaks show a small shift of the CT band as compared with microcrystalline layers. Raman spectra and XRD show that, even above 390 K, alpha-ET2I3 is formed in contrast to beta(co)-ET2I3 phase microcrystals formed above 370 K in solution. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：165 / 168

页数：4

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