Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

被引：267

作者：

Lin, Zhan ^{[1
]}

Liu, Zengcai ^{[2
]}

Fu, Wujun ^{[2
]}

Dudney, Nancy J. ^{[1
]}

Liang, Chengdu ^{[2
]}

机构：

[1] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA

[2] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 29期

关键词：

batteries; ionic conductivity; lithium; sulfidophosphates; sulfur; CATHODE MATERIALS; VIBRATIONAL-SPECTRA; PERFORMANCE; ELECTROLYTE; NANOTUBES; CELL;

D O I：

10.1002/anie.201300680

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sulfur-rich lithium polysulfidophosphates (LPSPs) act as an enabler for long-lasting and efficient lithium-sulfur batteries. LPSPs have ionic conductivities of 3.0×10-5 S cm-1 at 25 °C, which is 8 orders of magnitude higher than that of Li2S. The high lithium ion conductivity imparts excellent cycling performance, and the batteries are configured in an all-solid state, which promises safe cycling with metallic lithium anodes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7460 / 7463

页数：4

共 34 条

[1] Fast Li-circle plus conducting ceramic electrolytes [J].

Adachi, GY ;

Imanaka, N ;

Aono, H .

ADVANCED MATERIALS, 1996, 8 (02) :127-+

[2] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[3] RECHARGEABLE LITHIUM BATTERY ANODES - ALTERNATIVES TO METALLIC LITHIUM [J].

FAUTEUX, D ;

KOKSBANG, R .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1993, 23 (01) :1-10

[4] Effects of Liquid Electrolytes on the Charge-Discharge Performance of Rechargeable Lithium/Sulfur Batteries: Electrochemical and in-Situ X-ray Absorption Spectroscopic Studies [J].

Gao, Jie ;

Lowe, Michael A. ;

Kiya, Yasuyuki ;

Abruna, Hector D. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (50) :25132-25137

[5] Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium-Sulfur Batteries [J].

Guo, Juchen ;

Xu, Yunhua ;

Wang, Chunsheng .

NANO LETTERS, 2011, 11 (10) :4288-4294

[6] PVC disulfide as cathode materials for secondary lithium batteries [J].

Guo-xiang Xu ;

Lu Qi ;

Bi-tao Yu ;

Lei Wen .

CHINESE JOURNAL OF POLYMER SCIENCE, 2006, 24 (03) :307-313

[7] Moving to a Solid-State Configuration: A Valid Approach to Making Lithium-Sulfur Batteries Viable for Practical Applications [J].

Hassoun, Jusef ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2010, 22 (45) :5198-+

[8] Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries [J].

Ji, Liwen ;

Lin, Zhan ;

Alcoutlabi, Mataz ;

Zhang, Xiangwu .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (08) :2682-2699

[9]

Ji XL, 2009, NAT MATER, V8, P500, DOI [10.1038/NMAT2460, 10.1038/nmat2460]

[10]

Jung Y, 2008, INT J ELECTROCHEM SC, V3, P566

← 1 2 3 4 →