Asymmetric hydrolysis of alpha-alkylated cyclohexanone enol acetates by the cultured cells of Marchantia polymorpha

被引：11

作者：

Hirata, T

Shimoda, K

Ohba, D

Furuya, N

Izumi, S

机构：

[1] Department of Chemistry, Faculty of Science, Hiroshima University, Higashi-Hiroshima 739

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 16期

关键词：

D O I：

10.1016/S0957-4166(97)00329-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cultured suspension cells of Marchantia polymorpha hydrolyzed cyclohexanone enol acetates with 2-alkyl groups to afford optically active ketones. The stereoselectivity of the protonation of the enol intermediate was reversed when the chain length of alkyl substituents was increased. (C) 1997 Published by Elsevier Science Ltd.

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页码：2671 / 2673

页数：3

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