A technique to measure very low collisionless decay rates of ionic species has been applied at a new electrostatic storage ring to obtain the rate for spontaneous rearrangement of the vinylidene anion to neutral acetylene. The measurement yields a rate of k(0) = (0.009 +/- 0.006) s(-1), corresponding to a natural lifetime of the vinylidene anion uf tau(0) similar or equal to 110 s.